Gas Separation Using Furanic-Based Polymer Membranes – Project H2 2020

Executive Summary

Membrane gas separation is a financially significant and technologically critical component of the gas purification industry as it offers capital and operating cost advantages compared to other gas separation methods such as distillation, absorption, and adsorption. Many new polymer membrane materials have been proposed in recent years, but too often the cost of those materials and the inability to source commercial quantities prevent membrane manufacturers from developing new products. This project plans on addressing those drawbacks by introducing a new family of renewable, high-performance furanic-based polymers. Work in this project will focus on furanic-based polymer selection, hollow-fiber development, material characterization, and membrane testing for hydrogen recovery from mixed gas streams (e.g. H2/CO, H2/CO2, H2/N2/NH3) for commercial applications. Preliminary work on permeation tests has shown promising results, and the membrane separators have the potential to reduce capital costs by 10x, increase H2 recovery energy efficiency by 20% all while reducing the cost of separation by 20% and reducing waste by 20%.

Technical Challenge

  • More must be understood about the furanic-based polymer material in order to identify the optimal formulation(s) for gas separation
  • Understanding how the furanic-based polymer material behaves in the manufacture of hollow fibers
  • Achieving a high gas throughput and selectivity at a cost that is competitive with current technologies
     

Potential Impact

The hydrogen recovery market is an estimated $150 million in 2020 and the furanic-based polymer has a strong potential for application within said market. This technology could have a significant impact in the areas of H2 recovery from ammonia manufacturing, refinery H2 for hydrotreating and hydrocracking, and H2/CO synthesis gas adjustment.

Resources

The cross diciplinary project team will be lead by PI Mark Shiflett. KU will contribute various subject matter experts in computational chemistry and polymer materials characterization as well as their sophisticated lab testing equipment in conjunction with industry partners. DuPont will donate the furanic-based polymer membranes and materials  for testing. Hills, Inc. will lead the production of polymeric hollow fiber production and design of spinning equipment. Air Products will offer industrial expertise, donate membrane modules for testing,  monitor the project results and lead scale-up upon the end of the project if it proves successful.